Unfortunately there is currently no event available that is triggered when the user toggles streetview on the map. However this is a good suggestion and we'll investigate if this functionality can be added in a future version.
Please note that StreetViewOptions Heading/Pitch/Zoom are only updated when the StreetView is initialized. You can trigger the initialization after updating the Heading/Pitch/Zoom by hiding the StreetView and then making it visible again.