Problem with TWebCopy in 12.2.2.0

This is a behavior of the internally used TAnimate standard VCL class. It is not something in TWebCopy. It is related to how Embarcadero implemented TAnimate loading from resource.
If you run the EXE outside the IDE , you should not see the exception because in the VCL it is a gracefully added exception. The IDE always shows the exception unless you turn this off in the IDE in your DEBUG config.