There is a problem with TFlexCelReport.ReadBandValues which is in unit _FlexCelReport.FlexCelReport.pas
The problem is that FormatRangeList and FormatCellList aren't being initialized to nil.
There is a loop in this method, and the first thing that happens in the loop to these variables is
FreeObj(FormatRangeList); FreeObj(FormatCellList);
presumable to free objects created in the previous iteration of the loop. However, the first time though, in for us in 64 bit, FormatCellList is pointing to some random location in memory and that results in an access violation.