The following code works.
DIM Locator
DIM WMIServiceDIM Volume
DIM nError
Locator = CreateOleObject("WbemScripting.SWbemLocator")
WMIService = Locator.ConnectServer("", "root\CIMV2", "", "")
Volume = WMIService.ExecQuery("Select * from Win32_Volume WHERE Name='C:\\'")
showmessage("Caption: " & Volume.ItemIndex(0).Caption)
showmessage("DeviceID: " & Volume.ItemIndex(0).DeviceID)
Now I need to set DefragAnalysis parameters.